Question:

The ionisation energy of an electron in the ground state of helium atom is $24.6\, eV$. The energy required to remove both the electron is

Updated On: May 14, 2024
  • 51.8 eV
  • 79 eV
  • 38.2 eV
  • 49.2 eV
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The Correct Option is B

Approach Solution - 1

lonisation energy in ground state $=24.6 \,eV$
Energy required to remove $2^{n}$ electron from $He ^{2+}$
$=Z^{2}(13.6)\, eV =(2)^{2}(13.6)=54.4\, eV$
So, total energy required $=24.6+54.4=79\, eV$
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Approach Solution -2

A Helium atom contains two electrons. The amount of energy needed to remove the outermost electron from an atom is called its ionization energy.

We know that when one electron is removed from helium, the amount of energy needed is given as,

 

E1 = 24.6eV

 

This is the ionization potential of the helium atom. We also want to remove the other electrons from the helium atom. It looks like when one electron is removed from the helium then it turns into hydrogen-like which means it contains only 1 electron-like hydrogen atom.

Now we can calculate the energy using the Bohr model which is required to eliminate the second electron since now helium becomes hydrogen-like upon the removal of one electron. Therefore, we can use equation (i) where Z = 2 for the helium atom while n = 1 for the ground state of the electron.

E2 = 13.6×4/1 = 54.4eV

Hence the total amount of energy required to eliminate the 2 electrons from the helium atom is given as 

E = E1 + E2

= 24.6+54.4

= 78eV

 

Hence, the correct answer is option B.

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Concepts Used:

Bohr's Model of Hydrogen Atom

Niels Bohr introduced the atomic Hydrogen model in 1913. He described it as a positively charged nucleus, comprised of protons and neutrons, surrounded by a negatively charged electron cloud. In the model, electrons orbit the nucleus in atomic shells. The atom is held together by electrostatic forces between the positive nucleus and negative surroundings.

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Bohr's Theory of Hydrogen Atom and Hydrogen-like Atoms

A hydrogen-like atom consists of a tiny positively-charged nucleus and an electron revolving around the nucleus in a stable circular orbit. 

Bohr's Radius: 

If 'e,' 'm,' and 'v' be the charge, mass, and velocity of the electron respectively, 'r' be the radius of the orbit, and Z be the atomic number, the equation for the radii of the permitted orbits is given by r = n2 xr1, where 'n' is the principal quantum number, and r1 is the least allowed radius for a hydrogen atom, known as Bohr's radius having a value of 0.53 Å. 

Limitations of the Bohr Model

The Bohr Model was an important step in the development of atomic theory. However, it has several limitations.

  1. Bohr’s model of the atom failed to explain the Zeeman Effect (effect of magnetic field on the spectra of atoms).
  2. It failed to explain the Stark effect (effect of electric field on the spectra of atoms).
  3. The spectra obtained from larger atoms weren’t explained.
  4. It violates the Heisenberg Uncertainty Principle.