Consider the concentration cell
\[
\text{Pt} | \text{H}_2 (1 \, \text{bar}) | \text{HCl} (a_1) || \text{HCl} (a_2) | \text{H}_2 (1 \, \text{bar}) | \text{Pt}
\]
In concentration cells, the magnitude of liquid junction potential depends upon the transport number of cations and anions. For cells with \( a_2^+ \text{HCl} > a_1^+ \text{HCl} \), then the value of \( E_{ij} \) is negative when: