For a chlorine atom (\(Z=17\)), the ground state configuration is \( [Ne] 3s^2 3p^5 \).
The total spin quantum number is \(S = \frac{1}{2}\), and the orbital angular momentum quantum number is \(L = 1\) (p-orbital).
Using Hund's rules, the lowest energy state corresponds to \( ^2P_{3/2} \).