A rational function \( f(x) = \frac{P(x)}{Q(x)} \) is undefined when its denominator \( Q(x) \) is equal to zero.
In this case, \( f(x) = \frac{x^2 - 4x + 3}{x^2 - 5x + 6} \).
The denominator is \( Q(x) = x^2 - 5x + 6 \).
We need to find the values of \( x \) for which \( x^2 - 5x + 6 = 0 \).
Factorize the quadratic equation:
\[
x^2 - 5x + 6 = (x - 2)(x - 3)
\]
So, \( (x - 2)(x - 3) = 0 \).
This gives \( x - 2 = 0 \) or \( x - 3 = 0 \).
Therefore, \( x = 2 \) or \( x = 3 \).
The function is undefined at \( x = 2 \) and \( x = 3 \).
Now, check the numerator at these points to determine the type of discontinuity:
Numerator \( P(x) = x^2 - 4x + 3 = (x - 1)(x - 3) \).
At \( x = 2 \):
\[
P(2) = 2^2 - 4 \cdot 2 + 3 = 4 - 8 + 3 = -1
\]
\[
Q(2) = 0
\]
So, \( f(2) = \frac{-1}{0} \), which is undefined (vertical asymptote).
At \( x = 3 \):
\[
P(3) = 3^2 - 4 \cdot 3 + 3 = 9 - 12 + 3 = 0
\]
\[
Q(3) = 0
\]
So, \( f(3) = \frac{0}{0} \), which is indeterminate (removable discontinuity, or "hole").
For \( x \neq 3 \),
\[
f(x) = \frac{(x - 1)(x - 3)}{(x - 2)(x - 3)} = \frac{x - 1}{x - 2}
\]
However, the original function is still undefined at \( x = 3 \) due to division by zero in the original expression.
The function is defined for all real values of \( x \) except where the denominator is zero, i.e., \( x = 2 \) and \( x = 3 \).
\[
\boxed{\text{2 and 3}}
\]