Understand the polymer structures.
Poly(ethylene terephthalate) (PET) contains a benzene ring (aromatic group) in its backbone due to the presence of the terephthalic acid unit.
Polypropylene and Ultra-high molecular weight polyethylene are aliphatic polymers with no aromatic rings.
Polyacrylonitrile contains a nitrile group, but not an aromatic ring in the main chain.
Therefore, only PET contains an aromatic group in the main chain.