The turning moment (torque) can be calculated using the formula:
\[
T = F \times r \times \sin(\theta)
\]
where:
- \( F = 35 \, \text{kN} \) is the net force acting on the piston,
- \( r = 250 \, \text{mm} = 0.25 \, \text{m} \) is the crank radius,
- \( \theta = 100^\circ \) is the angle between the connecting rod and the crank.
Substitute the values into the formula:
\[
T = 35 \times 0.25 \times \sin(100^\circ)
\]
\[
T = 35 \times 0.25 \times 0.9848 = 8.00 \, \text{kN m}.
\]
Thus, the turning moment of the crank shaft is approximately \( \boxed{8.00} \, \text{kN m} \) (rounded to two decimal places).