The coordination number refers to the number of nearest neighboring atoms surrounding a given atom in a unit cell. Higher coordination numbers typically indicate more efficient packing, as atoms are packed more closely together.
- Body-Centered Cubic (BCC): The coordination number is 8, as each atom is surrounded by 8 nearest neighbors.
- Face-Centered Cubic (FCC): The coordination number is 12, as each atom is surrounded by 12 nearest neighbors.
- Hexagonal Close-Packed (HCP): The coordination number is also 12, similar to FCC, as atoms are arranged in the most efficient packing configuration.
Conclusion:
The correct order of coordination numbers is \( 8, 12, 12 \) for BCC, FCC, and HCP, respectively.