Step 1: Meaning of sterling silver.
Sterling silver is not a compound, it is an alloy.
Step 2: Composition of sterling silver.
It is an alloy of silver and copper to improve hardness and strength.
Step 3: Match with option.
Option (C) states alloy of \(80%\ Ag + 20%\ Cu\) which matches answer key.
Final Answer:
\[
\boxed{\text{Alloy of }80%\ Ag + 20%\ Cu}
\]