Huygens’ Principle and Angle of Reflection
Huygens’ principle states that every point on a wavefront acts as a source of secondary wavelets, which spread out in all directions with the same speed as the wave. The new wavefront is the envelope of these secondary wavelets.
Diagram:
In the diagram, consider:
The incident wavefront $AB$ approaching the reflecting surface at an angle $\theta_i$,
The reflected wavefront $CD$ leaving the surface at an angle $\theta_r$.
From the geometry of the wavefronts: \[ \theta_r = \theta_i. \] Thus, the angle of reflection equals the angle of incidence, as derived geometrically using Huygens’ principle.
A certain reaction is 50 complete in 20 minutes at 300 K and the same reaction is 50 complete in 5 minutes at 350 K. Calculate the activation energy if it is a first order reaction. Given: \[ R = 8.314 \, \text{J K}^{-1} \, \text{mol}^{-1}, \quad \log 4 = 0.602 \]