Aluminium has inherently poor sinterability due to the presence of a stable oxide layer — aluminium oxide (\( \text{Al}_2\text{O}_3 \)) — on its surface.
This oxide layer is:
- Thermodynamically stable,
- Very thin yet highly protective,
- Difficult to break down during the sintering process.
As a result, it prevents effective metallurgical bonding between particles during sintering, even at elevated temperatures.
Other options:
- The soft nature of aluminium does not hinder sintering.
- Compressibility of aluminium is generally good.
- Thermal conductivity affects heat distribution but is not the primary reason for poor sinterability.
Hence, the dominant factor is the persistent oxide barrier on aluminium powder particles.