Question:

Sc(Z = 21) is a transition element but Zn (Z = 30) is not because :

Updated On: May 5, 2024
  • Both $Sc^{3+}$ and $Zn^{2+}$ ions are colourless and form white compounds
  • In case of $Sc, 3d$ orbitals are partially filled but in $Zn$ these are filled
  • Last electron is assumed to be added to 4s level in case of Zn
  • Both Sc and Zn do not exhibit variable oxidation states
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The Correct Option is B

Solution and Explanation

Sc $(Z=21)$ has incompletely filled $3 d$-orbitals in its ground state $\left(3 d^{1}\right)$, it is considered as a transition element but $Zn ( Z =30)$ has completely filled d-orbitals $\left(3 d ^{10}\right)$ in its ground state and its common oxidation state of $(+2)$, it is not considered as a transition element.
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Concepts Used:

D and F Block Elements

The d-block elements are placed in groups 3-12 and F-block elements with 4f and 5f orbital filled progressively. The general electronic configuration of d block elements and f- block elements are (n-1) d 1-10 ns 1-2 and (n-2) f 1-14 (n-1) d1 ns2 respectively. They are commonly known as transition elements because they exhibit multiple oxidation states because of the d-d transition which is possible by the availability of vacant d orbitals in these elements. 

They have variable Oxidation States as well as are good catalysts because they provide a large surface area for the absorption of reaction. They show variable oxidation states to form intermediate with reactants easily. They are mostly lanthanoids and show lanthanoid contraction. Since differentiating electrons enter in an anti-penultimate f subshell. Therefore, these elements are also called inner transition elements.

Read More: The d and f block elements