Question:

Roasting of copper pyrite ores is for the following purpose

Updated On: Jul 7, 2022
  • to burn off sulphur, arsenic, antimony etc. as oxides and convert all the iron and copper to their oxides
  • to burn off arsenic, antimony etc. as oxides and burn off sulphur so that enough of it remains to combine with all the copper
  • to burn off sulphur partially, in order to leave enough of sulphur to combine with arsenic, antimony etc. and to convert all the iron and copper to oxides
  • to melt arsenic and antimony sulphides etc. and remove them by liquation and to burn off sulphur partially to leave enough to combine with copper and iron
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The Correct Option is C

Solution and Explanation

Roasting: The process in which the concentrated ore is heated in blast of air and ore gets converted into oxide and impurities like sulphur, arsenic are also oxidised to their oxides and removed is called Roasting. It requires very high temperature and specialized furnace like Bessemer or reverberatory furnace. Rreaction: $Cu _{2} S . Fe _{2} S _{3}+ O _{2} \rightarrow Cu _{2} S +2 F eS + SO _{2}$ $Cu _{2} S +3 O _{2} \rightarrow Cu _{2} O +2 SO _{2}$
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Concepts Used:

Concentration of Ore

The concentration of ore, also known as ore enrichment, is the process of removing gangue particles from ore in order to enhance the percentage of metal in the ore. The difference in physical or chemical properties of the ore and the impurities determines the procedures used to remove impurities from the ores. 

Methods of Concentration of Ore:

  • Hand-picking - It was the traditional system of directly concentrating ore with the hands. With the use of a hammer, the gangue or adhering solid matrix is removed from the ore in this procedure. The separation and identification of gangue are based on colour or lump form differences.
  • Hydraulic Washing - On passing the ore via an upward stream of water, the lighter gangue particles are separated from the heavier metal ore. This is a gravity separation method.This process is used to enrich ores that are heavier than the gangue particles that are present in them. A stream of water is run through crushed and finely powdered ore in this procedure. Water washes away the lighter gangue particles, leaving the larger ore particles behind.
  • Froth Floatation Process - The purpose of this process is to extract gangue from sulfide ores. The ore is pulverized and mixed with water to form a suspension. Collectors and Froth Stabilizers are added to this. Collectors like pine oils, fatty acids, etc. boost the metal part of the ore’s non-wettability, allowing it to form a froth.