Question:

Oxidation state of central metal atom in the given complex is: \[ [Co(NH_3)_4(H_2O)_2]Cl_3 \]

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For coordination complexes, neutral ligands don’t affect the oxidation state calculation. Only the counter ions matter.
  • \( +2 \)
  • \( +3 \)
  • \( +1 \)
  • \( +4 \)
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The Correct Option is B

Solution and Explanation

Step 1: Let the oxidation state of Co be \( x \).
\[ 4(NH_3) + 2(H_2O) + Co + 3Cl^- = 0 \] Step 2: \( NH_3 \) and \( H_2O \) are neutral ligands, so they contribute zero charge.
Chloride ion has a charge of \( -1 \) each. Total charge of three Cl\(^-\) is \(-3\).
\[ x + 0 - 3 = 0 \quad \Longrightarrow \quad x = +3 \]
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