(i) In Free State: Gold (Au) is found in free state in the Earth's crust. It is one of the least reactive metals and is placed low in the reactivity series.
(ii) In Compound Form: Aluminium (Al) is found in the form of its compound, such as in bauxite. It is a highly reactive metal and is placed high in the reactivity series.
Thus, gold is placed low in the reactivity series, while aluminium is placed high in the reactivity series.