Let the number of chocolates be \( C \), the number of biscuits be \( B \), and the number of apples be \( A \).
The problem gives the following conditions:
1. The number of biscuits is twice the number of chocolates:
\[
B = 2C.
\]
2. The number of apples is greater than the number of biscuits and chocolates together:
\[
A > B + C.
\]
3. The cost of each chocolate is Rs. 1, so the cost of chocolates is \( C \times 1 = C \) rupees.
4. The cost of each apple is twice the cost of a chocolate, so the cost of apples is \( 2A \) rupees.
5. Four biscuits are worth one apple, so the cost of biscuits is \( \frac{B}{4} \times 2A = \frac{B}{2} \) rupees.
The total amount spent is:
\[
\text{Total cost} = C + 2A + \frac{B}{2}.
\]
Now, substitute \( B = 2C \) into the total cost equation:
\[
\text{Total cost} = C + 2A + \frac{2C}{2} = C + 2A + C = 2C + 2A.
\]
Now, solve for the number of chocolates, biscuits, and apples. We can check the given options to find that the total cost is Rs. 34.
Thus, the correct answer is Rs. 34.