Question:

Molarity equation of a mixture of solutions of same substance is given by

Updated On: Oct 19, 2024
  • $M_{1}+V_{1}\times M_{2}+V_{2}\times M_{3}+V_{3}+...= M_{1}+M_{2}+M_{3}$
  • $M_{1}V_{1}+M_{2}V_{2}+M_{3}V_{3}+...=M\left(V_{1}+V_{2}+V_{3}\right)$
  • $\frac{M_{1}}{V_{1}}+\frac{M_{2}}{V_{2}}+\frac{M_{3}}{V_{3}}+ ... = M\left(\frac{1}{V_{1}}+\frac{1}{V_{2}}+\frac{1}{V_{3}}\right)$
  • $\frac{M_{1}}{V_{1}}\times\frac{M_{2}}{V_{2}}\times\frac{M_{3}}{V_{3}}+ ... = M\left(\frac{1}{V_{1}}\times\frac{1}{V_{2}}\times\frac{1}{V_{3}}\right)$
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The Correct Option is B

Solution and Explanation

Molarity, $M =$ number of moles/volume of solution $M=\frac{n}{V}$ for mixture of solutios $n _{1}+ n _{2}+ n _{3}+\ldots= M _{1} V _{1}+ M _{2} V _{2}+ M _{3} V _{3}+\ldots$ $\left( n _{1}+ n _{2}+ n _{3}+\ldots\right) \times \frac{\left( V _{1}+ V _{2}+ V _{3}+\ldots\right)}{\left( V _{1}+ V _{2}+ V _{3}+\ldots\right)}= M _{1} V _{1}+ M _{2} V _{2}+ M _{3} V _{3}+\ldots$ total number of moles in the mixture $=n_{ T }$, total volume $=V_{ T }$ final molarity $= M _{ T }= M$ $\frac{ n _{ T }}{ V _{ T }} \times\left( V _{1}+ V _{2}+ V _{3}+\ldots\right)= M _{1} V _{1}+ M _{2} V _{2}+ M _{3} V _{3}+\ldots$ $M _{ T } \times\left( V _{1}+ V _{2}+ V _{3}+\ldots\right)= M _{1} V _{1}+ M _{2} V _{2}+ M _{3} V _{3}+\ldots$ or $M \times\left( V _{1}+ V _{2}+ V _{3}+\ldots\right)= M _{1} V _{1}+ M _{2} V _{2}+ M _{3} V _{3}+\ldots$
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Concepts Used:

Concentration of Solutions

It is the amount of solute present in one liter of solution.

Concentration in Parts Per Million - The parts of a component per million parts (106) of the solution.

Mass Percentage - When the concentration is expressed as the percent of one component in the solution by mass it is called mass percentage (w/w).

Volume Percentage - Sometimes we express the concentration as a percent of one component in the solution by volume, it is then called as volume percentage

Mass by Volume Percentage - It is defined as the mass of a solute dissolved per 100mL of the solution.

Molarity - One of the most commonly used methods for expressing the concentrations is molarity. It is the number of moles of solute dissolved in one litre of a solution.

Molality - Molality represents the concentration regarding moles of solute and the mass of solvent.

Normality - It is the number of gram equivalents of solute present in one liter of the solution and it is denoted by N.

Formality - It is the number of gram formula present in one litre of solution.