Question:

Methyl benzoate can be prepared by

Updated On: Aug 7, 2023
  • $C _{6} H _{5} COOH + CH _{3} OH \xrightarrow{ H ^{+}}$
  • $C _{6} H _{5} COOCl + CH _{3} OH \xrightarrow{\text { Pyridine }}$
  • $C _{6} H _{5} COOH + CH _{2} N _{2} \rightarrow$
  • All of the above method
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The Correct Option is D

Approach Solution - 1

${C_6}{H_5}COOH + C{H_3}OH\xrightarrow{{H^+ }} \underset{\text{methyl benzoate}}{{C_6}{H_5}COOHC{H_3}} + {H_2}O$ (The reaction is methyl benzoate known as Fischer - Sprier esterification reaction.) ${C_6}{H_5}COCl + C{H_3}OH\xrightarrow{\text{Pyridine }}{C_6}{H_5}COOC{H_3} + HCl$ $C _{6} H _{5} COOH +\underset{\text { diazomethane }}{ CH _{2}} \xrightarrow{ N _{2}} C _{6} H _{5} COOCH _{3}+ N _{2}$ (Methyl easters can be prepared by treating carboxylic acid with ethereal solution of diazomethane. Hence, methyl benzoate can be prepared by all these above methods.
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Ans. Methyl benzoate is created when benzoic acid and methanol condense in the presence of a strong acid

  • Methyl benzoate is an organic compound, an ester with the chemical formula C6H5CO2CH3
  • When dissolved in a liquid, methyl benzoate can take the form of a solid or a crystalline solid. than water, but denser. 
  • Contact may cause mild irritation to mucous membranes, eyes, and skin. 
  • By consumption, it could be somewhat hazardous. used to produce different compounds. 
  • Methyl benzoate, a benzoate ester, is created when methanol and benzoic acid are combined. 
  • It serves as an insect attractant and metabolite.
  • It is both a methyl ester and a benzoate ester. 
  • In the Fischer Esterification reaction mechanism, an ester is formed by the conversion of carboxylic acid in the presence of excess alcohol and a strong acid as catalysts. 
  • The reaction was discovered by Emil Fischer.
  • Some disadvantages of the Fischer esterification reaction are:
  1. The thermodynamic reversibility of the reaction.
  2. The reaction rates are quite slow.
  • An energy source is usually needed to promote the Fischer esterification reaction. 
  • This energy is usually supplied in the form of heat.
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Concepts Used:

Aldehydes, Ketones, and Carboxylic Acids

Aldehydes, Ketones, and Carboxylic Acids are carbonyl compounds that contain a carbon-oxygen double bond. These organic compounds are very important in the field of organic chemistry and also have many industrial applications.

Aldehydes:

Aldehydes are organic compounds that have the functional group -CHO.

Preparation of Aldehydes

Acid chlorides are reduced to aldehydes with hydrogen in the presence of palladium catalyst spread on barium sulfate.

Ketones:

Ketones are organic compounds that have the functional group C=O and the structure R-(C=O)-R’.

Preparation of Ketones

Acid chlorides on reaction with dialkyl cadmium produce ketones. Dialkyl cadmium themselves are prepared from Grignard reagents.

Carboxylic Acid:

Carboxylic acids are organic compounds that contain a (C=O)OH group attached to an R group (where R refers to the remaining part of the molecule).

Preparation of Carboxylic Acids

Primary alcohols are readily oxidized to carboxylic acids with common oxidizing agents such as potassium permanganate in neutral acidic or alkaline media or by potassium dichromate and chromium trioxide in acidic media.