Question:

Mesomeric effect involves

Updated On: Apr 11, 2024
  • delocalisation of $\pi$ -electrons
  • delocalisation of $\sigma$-electrons
  • partial displacement of electrons
  • delocalisation of $\pi$ and $\sigma-$ electrons
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The Correct Option is A

Solution and Explanation

Resonance or mesomeric effect is defined as, the polarity produced in the molecule by the interaction of two $\pi$ -bonds or between a $\pi$ -bond and a lone pair of electrons present on an adjacent atom. There are $+M$ effect is observed when direction of electron displacement is away from an atom or substituent group attached to the conjugated system e.g. - halogen, $- OH _{1}- NH _{2}$ etc. On the other hand, $-M$ effect is observed when the transfer of electrons is towards the atom or substituent group attached to the conjugted systems, e.g., $- NO _{2},- COOH$ etc.
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Top Questions on Organic Chemistry- Some Basic Principles and Techniques

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Concepts Used:

Organic Chemistry – Some Basic Principles and Techniques - Reaction Mechanism

SN1 Reaction Mechanism:

SN1 reaction mechanism takes place by following three steps –

  • Formation of carbocation 
  • Attack of nucleophile 
  • Deprotonation 

SN2 Reaction Mechanism:

The SN2 reaction mechanism involves the nucleophilic substitution reaction of the leaving group (which generally consists of halide groups or other electron-withdrawing groups) with a nucleophile in a given organic compound.

Electrophilic Aromatic Substitution Reaction Mechanism:

The mechanism of an electrophilic aromatic substitution reaction contains three main components which are:

  1. A new sigma bond from C=C is formed during the reaction in the arene nucleophile.
  2. Due to the breaking of the C-H sigma bond, a proton is removed.
  3. The C=C bond is reformed and it restores the aromaticity of the compound.

Electrophilic Substitution Reaction Mechanism:

The electrophilic substitution reaction mechanism is composed of three steps, which will be discussed more below.

  • Electrophile Generation
  • Carbocation Formation
  • Proton Removal