Step 1: Understanding protein functions.
Proteins are classified based on their biological roles such as structure, movement, transport, and defense.
Step 2: Matching Column-I with Column-II.
Structural protein: Keratin provides structural strength to hair and skin, so a-(iii).
Contractile protein: Myosin is involved in muscle contraction, so b-(iv).
Transport protein: Myoglobin helps in oxygen transport and storage, so c-(ii).
Defensive protein: Immunoglobulins function in immune defense, so d-(i).
Step 3: Conclusion.
The correct matching is a-(iii), b-(iv), c-(ii), d-(i), which corresponds to option (D).