In this question, we are matching elements in Group I with their correct classification in Group II based on their affinity to different types of elements in nature. These classifications are related to the geochemical behavior of the elements.
- Cs (P): Cesium is an alkali metal and has a high affinity for lithosphere elements like silicon and oxygen, making it a lithophile. Hence, P corresponds to 4.
- Au (Q): Gold is a siderophile, meaning it has a strong affinity for iron and tends to associate with metals in the earth's core. Therefore, Q corresponds to 1.
- Cd (R): Cadmium is a chalophile, which prefers to bond with sulfur in sulfide minerals. Hence, R corresponds to 2.
- Rn (S): Radon, a noble gas, is highly atmophilic, meaning it is associated with gases in the atmosphere. Thus, S corresponds to 3.
Therefore, the correct matching is (A): P-4, Q-1, R-2, S-3.