Step 1: Rice blast disease (P)
The most serious rice disease worldwide is Blast, caused by the fungus Magnaporthe grisea (also called Pyricularia oryzae). This matches with option (5).
Step 2: False smut of rice (Q)
False smut is caused by the fungus Ustilaginoidea virens, which converts grains into large greenish or yellow spore balls. This matches with option (3).
Step 3: Sheath blight of rice (R)
Sheath blight is caused by the soil-borne fungus Rhizoctonia solani, which infects the leaf sheath near water level. This matches with option (2).
Step 4: Downy mildew of rice (S)
Downy mildew is caused by Sclerophthora macrospora, an oomycete pathogen. This matches with option (1).
Therefore, the correct matching is:
P-5; Q-3; R-2; S-1.