Question:

Match each type of reduction to its reagent:

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Always associate the type of reduction with the environment and reagents. Clemmensen is acidic, Wolff-Kishner is basic, and Rosenmund uses palladium.
  • Clemmensen Reduction → Zinc amalgam with hydrochloric acid
  • Wolff-Kishner Reduction → Hydrazine and potassium hydroxide with heat
  • Rosenmund Reduction → Hydrogen gas with palladium on barium sulfate
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The Correct Option is A

Solution and Explanation

Step 1: Understanding each reduction.
- Clemmensen reduction is carried out under acidic conditions, typically using zinc amalgam and hydrochloric acid.
- Wolff-Kishner reduction is performed under basic conditions, using hydrazine and potassium hydroxide with heat.
- Rosenmund reduction involves hydrogen gas and palladium on barium sulfate, often used to reduce acyl chlorides to aldehydes.
Step 2: Conclusion.
Thus, the correct matches are: (A) Clemmensen Reduction → Zinc amalgam with hydrochloric acid (B) Wolff-Kishner Reduction → Hydrazine and potassium hydroxide with heat (C) Rosenmund Reduction → Hydrogen gas with palladium on barium sulfate
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