Step 1: Use the diffraction grating equation.
The diffraction condition for a grating is given by Bragg’s law:
\[
n\lambda = d \sin \theta
\]
where \( n \) is the diffraction order, \( \lambda \) is the wavelength of the light, \( d \) is the grating spacing, and \( \theta \) is the diffraction angle.
Step 2: Calculate the grating spacing.
The number of lines per centimeter is 4000, so the grating spacing \( d \) is:
\[
d = \frac{1}{4000} \, \text{cm} = \frac{1}{4000 \times 10^2} \, \text{m} = 2.5 \times 10^{-6} \, \text{m}
\]
Step 3: Apply the diffraction equation.
For the third-order maximum (\( n = 3 \)) and wavelength \( \lambda = 680 \, \text{nm} = 680 \times 10^{-9} \, \text{m} \):
\[
3 \times 680 \times 10^{-9} = 2.5 \times 10^{-6} \sin \theta
\]
Solving for \( \theta \):
\[
\sin \theta = \frac{3 \times 680 \times 10^{-9}}{2.5 \times 10^{-6}} = 0.816
\]
\[
\theta = \sin^{-1}(0.816) = 21.04^\circ
\]
Step 4: Conclusion.
Thus, the diffraction angle corresponding to the third-order maximum is 21.04°.