The first maximum in a single-slit diffraction pattern occurs when the angle \(\theta\) satisfies the condition:
\[
a \sin \theta = m\lambda \quad (m = 1)
\]
For the first maximum, this becomes:
\[
e \sin \left(\frac{\pi}{3}\right) = \lambda
\]
Using \(\sin \left(\frac{\pi}{3}\right) = \frac{\sqrt{3}}{2}\), we get:
\[
e \times \frac{\sqrt{3}}{2} = \lambda \quad \Rightarrow \quad e = \frac{\lambda}{\sqrt{3}}
\]