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The reaction of an alkylbenzene with HBr typically results in benzylic substitution, where the alkyl group is replaced by a bromine atom.
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Solution and Explanation

The reaction of toluene (methylbenzene) with HBr leads to the alkyl group (methyl) being substituted with a bromine atom at the benzylic position, forming 1-bromo-2-methylbenzene as the major product. The structure of the product is: \[ \text{C}_6\text{H}_4\text{CH}_2\text{Br} \] \vspace{10pt}
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