The change in internal energy (\( \Delta U \)) of a system is given by:
\[ \Delta U = n C_v \Delta T, \]
where:
In an isothermal process, the temperature of the system remains constant, so:
\[ \Delta T = 0. \]
Substitute \( \Delta T = 0 \) into the equation for \( \Delta U \):
\[ \Delta U = n C_v (0) = 0. \]
Since \( \Delta U = 0 \), the internal energy of the system does not change during an isothermal process.
In an isothermal process, the internal energy remains constant because the temperature does not change.
The thermodynamic process in which internal energy remains constant is isothermal.
The ratio of the fundamental vibrational frequencies \( \left( \nu_{^{13}C^{16}O} / \nu_{^{12}C^{16}O} \right) \) of two diatomic molecules \( ^{13}C^{16}O \) and \( ^{12}C^{16}O \), considering their force constants to be the same, is ___________ (rounded off to two decimal places).}
A heat pump, operating in reversed Carnot cycle, maintains a steady air temperature of 300 K inside an auditorium. The heat pump receives heat from the ambient air. The ambient air temperature is 280 K. Heat loss from the auditorium is 15 kW. The power consumption of the heat pump is _________ kW (rounded off to 2 decimal places).
The total number of structural isomers possible for the substituted benzene derivatives with the molecular formula $C_7H_{12}$ is __
Four capacitors each of capacitance $16\,\mu F$ are connected as shown in the figure. The capacitance between points A and B is __ (in $\mu F$)
Among, Sc, Mn, Co and Cu, identify the element with highest enthalpy of atomisation. The spin only magnetic moment value of that element in its +2 oxidation state is _______BM (in nearest integer).
X g of nitrobenzene on nitration gave 4.2 g of m-dinitrobenzene. X =_____ g. (nearest integer) [Given : molar mass (in g mol\(^{-1}\)) C : 12, H : 1, O : 16, N : 14]
A perfect gas (0.1 mol) having \( \bar{C}_V = 1.50 \) R (independent of temperature) undergoes the above transformation from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is ____ J (nearest integer) [Given : R = 0.082 L atm K\(^{-1}\)]
Thermodynamics in physics is a branch that deals with heat, work and temperature, and their relation to energy, radiation and physical properties of matter.
A thermodynamic system is a specific portion of matter with a definite boundary on which our attention is focused. The system boundary may be real or imaginary, fixed or deformable.
There are three types of systems:
A system undergoes a thermodynamic process when there is some energetic change within the system that is associated with changes in pressure, volume and internal energy.
There are four types of thermodynamic process that have their unique properties, and they are:
The Zeroth law of thermodynamics states that if two bodies are individually in equilibrium with a separate third body, then the first two bodies are also in thermal equilibrium with each other.
The First law of thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes, distinguishing three kinds of transfer of energy, as heat, as thermodynamic work, and as energy associated with matter transfer, and relating them to a function of a body's state, called internal energy.
The Second law of thermodynamics is a physical law of thermodynamics about heat and loss in its conversion.
Third law of thermodynamics states, regarding the properties of closed systems in thermodynamic equilibrium: The entropy of a system approaches a constant value when its temperature approaches absolute zero.