Question:

In hydrogen atom, energy of first excited state is -3.4 eV. Then, KE of same orbit of hydrogen atom :-

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Total energy \((E_n)\)\(KE + PE\) 

Updated On: Apr 7, 2024
  • +3.4 eV

  • +6.8 eV

  • -13.6 eV
  • +13.6 eV

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The Correct Option is A

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In hydrogen atom, energy of first excited state is -3.4 eV

Then, KE of same orbit of hydrogen atom can be determined by:

\(\because\) Total energy \((E_n)\)\(KE + PE\) 
In first excited state\(=\frac{1}{2}mv^2+\Bigg[-\frac{Ze^2}{r}\Bigg]\)
\(\hspace15mm =+\frac{1}{2}\frac{Ze^2}{r}-\frac{Ze^2}{r}\) 

\(\, \, \, \, \, \, \, \, \, \, \, \, \, \, \, - 3.4 eV =-\frac{1}{2}\frac{Ze^2}{r}\)
\(\therefore \, \, \, \, \, \, \, \, \, \, \, \, \, KE=\frac{1}{2}\frac{Ze^2}{r}\) 
\(+\, 3.4 \,eV\)

So, Energy of first excited state is 3.4 eV 

The kinetic energy of a particle is the form of energy that it possesses due to the motion of the particle. It is also defined as the work done in accelerating a particle of a given mass from rest to its stated velocity.

  • The motion of electrons, waves, atoms, substances, molecules, and objects are examples of kinetic energy.
  • A system of bodies that is the combination of many individual bodies may have internal kinetic energy due to the motion of individual bodies.
  • The SI unit of kinetic energy is joule (J).
  • The kinetic energy of a body of mass m moving with velocity v is given by
    K.E = 1/2 mv2

Discover more from this chapter: Structure of Atom

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Approach Solution -2

The correct answer is Option A) +3.4 eV

Real Life Applications

  • The application of the kinetic energy of the electron is as follows:
  • To understand the emission spectrum of hydrogen. They are the lines that are generated when the electron moves from one state to another ( from excited to ground state). Lasers are used to generate light that is of a specific wavelength. To create a laser kinetic energy of an electron should be known.
  • The atoms in the material are affected by the electric field generated. To study the properties of materials kinetic energy of electrons are studied.
Hydrogen atom

Question can also be asked as

  1. What is the kinetic energy of an electron in the first excited state of a hydrogen atom?
  2. How is the kinetic energy of an electron related to the energy of the electron in an atom?
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All forms of energy may be divided into two main categories: kinetic energy, or energy resulting from an object's motion, and potential energy, or energy held inside a body.

  • The movement of electrons, waves, atoms, substances, molecules, and objects is a source of kinetic energy.
  • Due to its location, an item stores potential energy.
  • It can never be destroyed and may be kept in a variety of ways.
  • Chemical, thermal, nuclear, electrical, mechanical, and a host of other forms of energy exist.
  • Different units can be used to measure energy, and the SI unit for energy is the joule. 
  • Other widely used units of energy exist in addition to the SI units, including calories, horsepower, kilowatts, megawatts, and barrels.

Energy Level Formula

The Bohr Model of the hydrogen atom should be taken into account when calculating the rotational energy level formula.

  • In the standard model of the hydrogen atom, an assumption was made concerning the quantization of atoms.
  • According to this theory, electrons orbit the nucleus in orbits or shells with a fixed radius.
  • Only shells with a radius equal to the Energy Level Formula were permitted.
  • Additionally, no electrons can be present between the shells.
  • The mathematical expression for the permitted value of the atomic radius in the energy level is,
    r(n) = n2 + r(1)

As a result, the equation for energy state for radius is often known as Bohr's formula.
 

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Concepts Used:

Structure of Atom

Atomic Structure:

The atomic structure of an element refers to the constitution of its nucleus and the arrangement of the electrons around it. Primarily, the atomic structure of matter is made up of protons, electrons and neutrons.

Dalton’s Atomic Theory

Dalton proposed that every matter is composed of atoms that are indivisible and indestructible. 

The following are the postulates of his theory:

  • Every matter is made up of atoms.
  • Atoms are indivisible.
  • Specific elements have only one type of atoms in them.
  • Each atom has its own constant mass that varies from element to element.
  • Atoms undergo rearrangement during a chemical reaction.
  • Atoms can neither be created nor be destroyed but can be transformed from one form to another.

Cons of Dalton’s Atomic Theory

  • The theory was unable to explain the existence of isotopes.
  • Nothing about the structure of atom was appropriately explained.
  • Later, the scientists discovered particles inside the atom that proved, the atoms are divisible.

​​Subatomic Particles

  1. Protons - are positively charged subatomic particles.
  2. Electron - are negatively  charged subatomic particles.
  3. Neutrons - are electrically neutral particles and carry no charge

Atomic Structure of Isotopes

Several atomic structures of an element can exist, which differ in the total number of nucleons.These variants of elements having a different nucleon number (also known as the mass number) are called isotopes of the element. Therefore, the isotopes of an element have the same number of protons but differ in the number of neutrons.  For example, there exist three known naturally occurring isotopes of hydrogen, namely, protium, deuterium, and tritium.