Step 1: Understanding the phase difference in a capacitor.
In an alternating current (a.c.) circuit containing only a capacitor, the current leads the voltage by 90°. This is because the voltage across the capacitor lags the current due to the charging and discharging of the capacitor.
Step 2: Conclusion.
Thus, the phase difference between the current and voltage in a purely capacitive circuit is 90°.
\[
\boxed{90^\circ}
\]