To solve for the total number of children standing in a circle when the 6th child is diametrically opposite the 16th child, we need to determine the total number of children \( n \) in the circle.
In a circle, if one person is diametrically opposite to another, the total number of people between them is half of the circumference. The formula used is:
\[ \text{Position of } B = \text{Position of } A + \frac{n}{2} \mod n \]
Here, the 16th child (B) is opposite the 6th child (A). Thus:
\[ 16 = 6 + \frac{n}{2} \mod n \]
Simplifying, we get:
\[ 16 - 6 = \frac{n}{2} \]
\[ 10 = \frac{n}{2} \]
Multiply both sides by 2 to solve for \( n \):
\[ n = 20 \]
Therefore, the total number of children in the circle is 20.