Question:

In a process, the work done by the system is equal to the decrease in its internal energy. The process that the system undergoes is: 

Updated On: Apr 11, 2025
  • isothermal process

  • adiabatic process

  • isobaric process

  • isochoric process

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The Correct Option is B

Approach Solution - 1

To solve the problem, we need to identify the thermodynamic process in which the work done by the system is equal to the decrease in its internal energy.

1. Understanding the First Law of Thermodynamics:
The first law states:
$ \Delta Q = \Delta U + W $
Where:
- $\Delta Q$ is the heat added to the system
- $\Delta U$ is the change in internal energy
- $W$ is the work done by the system

2. Given Condition:
The system does work, and the decrease in internal energy is equal to the work done. That is:
$ W = -\Delta U $
Substitute into the first law:
$ \Delta Q = \Delta U + W = \Delta U - \Delta U = 0 $

3. Conclusion from Zero Heat Transfer:
If $ \Delta Q = 0 $, it means no heat is exchanged with the surroundings. This is the definition of an adiabatic process.

Final Answer:
The process is an adiabatic process.

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Approach Solution -2

The correct option is: (B): adiabatic process.

In line with the first law of thermodynamics, the equation states that:

dQ = dU + dW

Given that dW = -dU, it follows that:

dQ = 0

As a result, the heat transfer within the system equals zero. Consequently, this implies the process could be adiabatic.

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Concepts Used:

Kinetic Molecular Theory of Gases

Postulates of Kinetic Theory of Gases:

  • Gases consist of particles in constant, random motion. They continue in a straight line until they collide with each other or the walls of their container. 
  • Particles are point masses with no volume. The particles are so small compared to the space between them, that we do not consider their size in ideal gases.
  • Gas pressure is due to the molecules colliding with the walls of the container. All of these collisions are perfectly elastic, meaning that there is no change in energy of either the particles or the wall upon collision.  No energy is lost or gained from collisions. The time it takes to collide is negligible compared with the time between collisions.
  • The kinetic energy of a gas is a measure of its Kelvin temperature. Individual gas molecules have different speeds, but the temperature and
    kinetic energy of the gas refer to the average of these speeds.
  • The average kinetic energy of a gas particle is directly proportional to the temperature. An increase in temperature increases the speed in which the gas molecules move.
  • All gases at a given temperature have the same average kinetic energy.
  • Lighter gas molecules move faster than heavier molecules.