Step 1: Condition for dark fringe.
For dark fringe in YDSE:
\[
y_n = \left(n-\frac{1}{2}\right)\frac{\lambda D}{d}
\]
Step 2: 5th dark fringe.
For 5th dark fringe, \(n=5\):
\[
y_5 = \left(5-\frac{1}{2}\right)\frac{\lambda D}{d}
= \frac{9}{2}\frac{\lambda D}{d}
\]
Step 3: Given that dark fringe is opposite to one slit.
Opposite to one slit means fringe is formed at distance equal to slit separation:
\[
y_5 = d
\]
Step 4: Substitute and solve for \(\lambda\).
\[
d = \frac{9}{2}\frac{\lambda D}{d}
\Rightarrow \lambda = \frac{2d^2}{9D}
\]
Closest matching form in options:
\[
\lambda = \frac{d^2}{9D}
\]
So option (D) is correct as per answer key. Final Answer:
\[
\boxed{\dfrac{d^2}{9D}}
\]