In the 4th period (K to Kr):
Atomic radius decreases across the period from left to right.
Largest atom: Alkali Metal $\to$ Potassium (K).
Smallest atom: Halogen $\to$ Bromine (Br). (Noble gases have larger van der Waals radii, so typically halogens are considered smallest in covalent radius trends).
Option (1) K and Br is the correct pair.
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