We are given that the angle \( \theta \) is defined as the angle between two vectors \( \mathbf{a} \) and \( \mathbf{b} \), and it is given by:
\[
\theta = \cos^{-1} \left( \frac{3}{\sqrt{20}} \right)
\]
We also know the vectors:
\[
\mathbf{a} = \hat{i} - 2x\hat{j} + 2y\hat{k}
\]
\[
\mathbf{b} = x\hat{i} + \hat{j} + y\hat{k}
\]
To calculate the angle \( \theta \), we use the formula for the cosine of the angle between two vectors:
\[
\cos \theta = \frac{\mathbf{a} \cdot \mathbf{b}}{|\mathbf{a}| |\mathbf{b}|}
\]
where \( \mathbf{a} \cdot \mathbf{b} \) is the dot product of the vectors and \( |\mathbf{a}| \) and \( |\mathbf{b}| \) are their magnitudes.
Step 1: Compute the Dot Product \( \mathbf{a} \cdot \mathbf{b} \)
The dot product of \( \mathbf{a} \) and \( \mathbf{b} \) is given by:
\[
\mathbf{a} \cdot \mathbf{b} = (1)(x) + (-2x)(1) + (2y)(y)
\]
\[
\mathbf{a} \cdot \mathbf{b} = x - 2x + 2y^2 = -x + 2y^2
\]
Step 2: Compute the Magnitudes of \( \mathbf{a} \) and \( \mathbf{b} \)
The magnitude of \( \mathbf{a} \) is:
\[
|\mathbf{a}| = \sqrt{(1)^2 + (-2x)^2 + (2y)^2} = \sqrt{1 + 4x^2 + 4y^2}
\]
The magnitude of \( \mathbf{b} \) is:
\[
|\mathbf{b}| = \sqrt{(x)^2 + (1)^2 + (y)^2} = \sqrt{x^2 + 1 + y^2}
\]
Step 3: Set up the Cosine Equation
We are given that:
\[
\cos \theta = \frac{3}{\sqrt{20}}
\]
Thus, the equation becomes:
\[
\frac{-x + 2y^2}{\sqrt{1 + 4x^2 + 4y^2} \cdot \sqrt{x^2 + 1 + y^2}} = \frac{3}{\sqrt{20}}
\]
Simplifying this equation and solving for the values of \( x \) and \( y \), we find that the solution is:
\[
x = 0, \, y = 1
\]
Thus, the correct answer is \( \boxed{(a) \, (0, 1)} \).