Step 1: Using the Tangent Formula.
The slope of the tangent to the curve at a point is equal to the derivative of the function at that point. The angle \( \theta \) the tangent makes with the positive x-axis is related to the slope by:
\[
\tan \theta = f'(x)
\]
For \( \theta = \frac{3\pi}{4} \), we get \( \tan \left( \frac{3\pi}{4} \right) = -1 \). Therefore, \( f'(3) = -1 \).
Step 2: Conclusion.
The correct answer is (A), \( -1 \).