The given equation of the pair of lines is \(2x^2 + 3xy + Ky^2 = 0\).
We have the general form of the equation of pair of lines as \(ax^2 + 2hxy + by^2 = 0\).
Comparing, we identify \(a = 2\), \(2h = 3\) (hence \(h = \frac{3}{2}\)), and \(b = K\).
The condition for the slope \(m\) of one of the lines is given by the equation:
\(m = \frac{-h \pm \sqrt{h^2 - ab}}{b}\).
Substituting \(m = 2\):
\(2 = \frac{-\frac{3}{2} \pm \sqrt{\left(\frac{3}{2}\right)^2 - 2K}}{K}\).
Simplifying the equation:
\(2K = -\frac{3}{2} \pm \sqrt{\frac{9}{4} - 2K}\).
To find the value of \(K\), solve the equation:
\(-4K = -3 \pm \sqrt{9 - 8K}\).
Squaring both sides:
\(16K^2 = (3 \pm \sqrt{9 - 8K})^2 = 9 - 8K + 6\sqrt{9 - 8K}\).
This equation can get quite complex, so consider backtracking if calculations hit an impasse. Generally for simplicity, you'll find \(K\) where the existence condition returns smoothly.
Now, for \(\text{tan}(\theta)\) where \(\theta\) is the angle between the lines, use:
\(\tan(\theta) = \left|\frac{2\sqrt{h^2 - ab}}{a + b}\right|\).
Substitute known values to find
\(\tan(\theta) = \left|\frac{2\sqrt{\left(\frac{3}{2}\right)^2 - 2K}}{2 + K}\right|\).
This angle turns to \( \frac{\pi}{2} \) when lines are perpendicular.
Perpendicular lines imply \(a + b = 0 \Rightarrow 2 + K = 0\) which means \(K = -2\).
Thus, the correct answer is:
\( \frac{\pi}{2} \).