The temperature difference is the difference between the maximum and minimum temperatures:
$44^\circ C - 22^\circ C = 22^\circ C$
For the errors, when subtracting quantities with uncertainties, the absolute errors are added:
$0.5^\circ C + 0.5^\circ C = 1^\circ C$
So, the final result is: $22^\circ C \pm 1^\circ C$