Given:
\[
f(0) = f(1) = 0, \quad f'(0) = 0
\]
By Rolle’s Theorem applied on \([0,1]\), since \(f(0) = f(1)\), and \(f(x)\) is differentiable, there exists \(c \in (0,1)\) such that \(f'(c) = 0\). Now since \(f'(0) = 0\), apply Rolle’s Theorem again to \(f'\) on \([0,c]\) to get \(f''(x) = 0\) for some \(x \in (0,c) \subset (0,1)\).