Question:

If a surface has a work function $4.0 \,eV$, what is the maximum velocity of electrons liberated from the surface when it is irradiated with ultraviolet radiation of wavelength $0.2\, \mu m$ ?

Updated On: Jul 29, 2023
  • $4.4 \times 10^{5} \,m / s$
  • $ 8.8\times 10^{7}\,m/s $
  • $ 8.8\times 10^{5}\,m/s $
  • $ 4.4\times 10^{7}\,m/s $
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The Correct Option is B

Solution and Explanation

Work function \(W =4 eV =4 \times 1.6 \times 10^{-19} J\) \(=6.4 \times 10^{-19} J\) Wavelength of incident radiation \(\lambda=0.2 \mu m =0.2 \times 10^{-6} m\) Maximum KE of liberated electron \(( KE )_{\max }=\frac{h c}{\lambda}-W\) \(\frac{1}{2} m v_{\max }^{2}=\frac{h c}{\lambda}-W\) \(\frac{1}{2} \times 9.1 \times 10^{-31} v_{\max }^{2}\) \(=\frac{6.6 \times 10^{-34} \times 3 \times 10^{8}}{0.2 \times 10^{-6}}-6.4 \times 10^{-19}\) \(=9.9 \times 10^{-19}-6.4 \times 10^{-19}=3.5 \times 10^{-19}\) \(\therefore v_{\max }=\sqrt{\frac{3.5 \times 10^{-19} \times 2}{9.1 \times 10^{-31}}}=\sqrt{\frac{7}{9.1} \times 10^{12}}\) \(=8.8 \times 10^{5} m / s\)

The Photoelectric Effect is a phenomena in which an electron is emitted from a metallic surface when a beam of light touches it. Photoelectrons are the electrons that are released from the surface.

  • Photoelectric current is the term used to describe the current generated by photoelectrons.
  • The photoelectric effect is caused, in part, by the energy of light being absorbed by the electrons on the metal surface.
  • The forces holding the electrons to the metal nuclei are overcome by the electrons using this light energy.
  • Heinrich Rudolf Hertz, a German scientist, made the discovery of the photoelectric effect in 1887.
  • He discovered that UV illumination of the emitter plate promoted high-voltage sparks over the detector loop.
  • He came to the conclusion that light aided in some electron emission as a result of this discovery.
  • This led scientists to the conclusion that when the right kind of radiation strikes a metal surface, certain electrons nearby can absorb enough energy from the radiation to repel the positive ions that are attracted to the surface of the material.
  • In 1988, Wilhelm Hallwachs made the observation that the divergence of gold leaf is reduced by ultraviolet light shining on a negatively charged zinc plate linked to an electroscope.
  • He came to the conclusion that a negatively charged zinc plate releases negatively charged particles when exposed to ultraviolet light.
  • The photoelectrons that are released are caused by the action of light.
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Concepts Used:

Photoelectric Effect

When light shines on a metal, electrons can be ejected from the surface of the metal in a phenomenon known as the photoelectric effect. This process is also often referred to as photoemission, and the electrons that are ejected from the metal are called photoelectrons.

Photoelectric Effect Formula:

According to Einstein’s explanation of the photoelectric effect :

The energy of photon = energy needed to remove an electron + kinetic energy of the emitted electron

i.e. hν = W + E

Where,

  • h is Planck’s constant.
  • ν is the frequency of the incident photon.
  • W is a work function.
  • E is the maximum kinetic energy of ejected electrons: 1/2 mv².

Laws of Photoelectric Effect:

  1. The photoelectric current is in direct proportion to the intensity of light, for a light of any given frequency; (γ > γ Th).
  2. There exists a certain minimum (energy) frequency for a given material, called threshold frequency, below which the discharge of photoelectrons stops completely, irrespective of how high the intensity of incident light is.
  3. The maximum kinetic energy of the photoelectrons increases with the increase in the frequency (provided frequency γ > γ Th exceeds the threshold limit) of the incident light. The maximum kinetic energy is free from the intensity of light. 
  4. The process of photo-emission is an instantaneous process.