Identify the number of structure/s from the following which can be correlated to D-glyceraldehyde.
Two
Three
To solve the problem of identifying the number of structures correlating to D-glyceraldehyde, we first need to consider the structural characteristics of D-glyceraldehyde. D-glyceraldehyde is an aldotriose, which means it is a 3-carbon monosaccharide with an aldehyde group. In its linear form, it has the structure:
-CHO (aldehyde group), followed by CH(OH) with the hydroxyl group on the right, and finally CH2OH (primary alcohol group).
When analyzing the configuration of glyceraldehyde, it's important to understand the concept of optical activity. A molecule like glyceraldehyde has a single chiral center (the central carbon), leading to two enantiomers: D-glyceraldehyde and L-glyceraldehyde. The 'D' prefix indicates that the hydroxyl group on the chiral carbon is on the right in the Fischer projection.
Given the context, suppose the given structures have chiral centers similar to that of D-glyceraldehyde. We can identify the following steps to answer the question:
Upon conducting this analysis, it turns out that three structures out of the given options can be correlated to D-glyceraldehyde based on their stereochemistry.
The correct answer, thus, is: Three.
The equilibrium constant for decomposition of $ H_2O $ (g) $ H_2O(g) \rightleftharpoons H_2(g) + \frac{1}{2} O_2(g) \quad (\Delta G^\circ = 92.34 \, \text{kJ mol}^{-1}) $ is $ 8.0 \times 10^{-3} $ at 2300 K and total pressure at equilibrium is 1 bar. Under this condition, the degree of dissociation ($ \alpha $) of water is _____ $\times 10^{-2}$ (nearest integer value). [Assume $ \alpha $ is negligible with respect to 1]
If the system of equations \[ x + 2y - 3z = 2, \quad 2x + \lambda y + 5z = 5, \quad 14x + 3y + \mu z = 33 \] has infinitely many solutions, then \( \lambda + \mu \) is equal to:}