Question:

Identify the incorrect statement among the following

Updated On: Jul 2, 2022
  • $d$-Block elements show irregular and erratic chemical properties among themselves
  • $La$ and $Lu$ have partially filled $d$- orbitals and no other partially filled orbitals
  • The chemistry of various lanthanoids is very similar
  • $4\,f$ and $5\,f$ orbitals are equally shielded
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The Correct Option is D

Solution and Explanation

4f and 5f belongs to different energy levels, hence the shielding effect is on them is not the same. Shielding of 4f is more than 5f. Hence (4) is correct.
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Concepts Used:

D and F Block Elements

The d-block elements are placed in groups 3-12 and F-block elements with 4f and 5f orbital filled progressively. The general electronic configuration of d block elements and f- block elements are (n-1) d 1-10 ns 1-2 and (n-2) f 1-14 (n-1) d1 ns2 respectively. They are commonly known as transition elements because they exhibit multiple oxidation states because of the d-d transition which is possible by the availability of vacant d orbitals in these elements. 

They have variable Oxidation States as well as are good catalysts because they provide a large surface area for the absorption of reaction. They show variable oxidation states to form intermediate with reactants easily. They are mostly lanthanoids and show lanthanoid contraction. Since differentiating electrons enter in an anti-penultimate f subshell. Therefore, these elements are also called inner transition elements.

Read More: The d and f block elements