Question:

Identify the incorrect option from the following:

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Alcoholic KOH generally promotes elimination reactions (E2 mechanism), while aqueous KOH favors nucleophilic substitution reactions (SN2 or SN1)

Updated On: Jan 15, 2025
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The Correct Option is A

Solution and Explanation

Analysis of the Given Reactions:

  1. Option (1): The reaction involves alcoholic KOH, which promotes elimination (E2 mechanism). However, the product shown is incorrect because the major product should be a double bond formed due to elimination, not a substitution product
  2. Option (2): This is a Dow process, correctly showing the conversion of chlorobenzene to phenol under high temperature and pressure.
  3. Option (3): The reaction involves the substitution of −Br with −OH using aqueous KOH. This is a correct nucleophilic substitution reaction.
  4. Option (4): The reaction is a Friedel-Crafts acylation, which is correctly represented.

Conclusion: The incorrect reaction is Option (1).

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Concepts Used:

Alcohols, Phenols, and Ethers

Alcohol is formed when a saturated carbon atom bonds to a hydroxyl (-OH) group. It is an organic compound that contains a hydroxyl functional group attached to a carbon atom.

Phenol is formed when the -OH group replaces the hydrogen atom in benzene. It is an organic compound in which a hydroxyl group directly attaches to an aromatic hydrocarbon.

Ether is formed when oxygen atom bonds to two alkyl or aryl groups. It is an organic compound that has an oxygen atom that is connected to two aryl and alkyl groups.

Read More: Alcohol, Phenol, and Ethers