I, III only
Let's analyze the given statements:
Statement I: The order of the reaction is determined from experiment only.
This statement is correct. The order of a reaction cannot be predicted theoretically, and it must be determined experimentally based on reaction rates.
Statement II: The order of a reaction can be zero, a positive integer or a fraction.
This statement is also correct. The order of reaction can indeed be zero, a positive integer, or even a fraction, depending on the nature of the reaction.
Statement III: In a multistep reaction, the slow step determines the rate.
This statement is also true. In a multistep reaction, the slowest step, often referred to as the rate-determining step, governs the overall rate of the reaction.
Thus, all three statements are correct.
Given below are two statements regarding conformations of n-butane. Choose the correct option. 
Consider a weak base \(B\) of \(pK_b = 5.699\). \(x\) mL of \(0.02\) M HCl and \(y\) mL of \(0.02\) M weak base \(B\) are mixed to make \(100\) mL of a buffer of pH \(=9\) at \(25^\circ\text{C}\). The values of \(x\) and \(y\) respectively are