Question:

What is a rate determining step?

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In a reaction mechanism, the rate-determining step controls the speed of the overall reaction because it is the slowest step in the process.
Updated On: Jun 10, 2025
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Rate-Determining Step in a Reaction Mechanism

In a multi-step chemical reaction, the rate-determining step is the slowest elementary step in the reaction pathway. It acts as a bottleneck for the entire reaction process, meaning that the overall rate of the reaction is limited by the rate at which this step proceeds.

This step typically:

  • Has the highest activation energy among all the steps in the mechanism.
  • Occurs more slowly compared to the other steps.
  • Determines the overall reaction rate, regardless of how fast the other steps occur.

Therefore, even if the subsequent steps are fast, the reaction cannot proceed faster than the rate-determining step allows. Understanding which step this is can help chemists control and optimize reaction rates in practical applications such as industrial synthesis and catalysis.

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