Step 1: Straight chain amines.
1. n-Butylamine: CH$_3$–CH$_2$–CH$_2$–CH$_2$–NH$_2$
2. Isobutylamine: (CH$_3$)$_2$CH–CH$_2$–NH$_2$
Step 2: Branched chain amines.
3. sec-Butylamine: CH$_3$–CH(NH$_2$)–CH$_2$–CH$_3$
4. tert-Butylamine: (CH$_3$)$_3$C–NH$_2$
Step 3: Count unique structures.
Thus, four distinct primary amines are possible.
\[
\boxed{4}
\]
The descending order of basicity of following amines is :
Choose the correct answer from the options given below :
Which of the following amine(s) show(s) positive carbamylamine test? 
The correct order of basicity for the following molecules is: 