Step 1: Purpose of toluene in esterification.
Toluene is used as a solvent in esterification reactions because it helps dissolve both the alcohol and the acid, making the reaction more efficient.
Step 2: Conclusion.
Thus, the correct answer is option (A).
Final Answer:
\[
\boxed{\text{(A) to make both substances (acid and alcohol) miscible}}
\]