In an
intrinsic semiconductor, conductivity is primarily determined by the thermal excitation of electrons from the valence band to the conduction band. As temperature increases, more electrons gain enough energy to cross the band gap, thereby increasing the number of charge carriers (electrons and holes). This leads to a significant
increase in electrical conductivity with temperature.
In contrast, metals exhibit a decrease in conductivity with temperature because increased thermal vibrations scatter conduction electrons more, increasing resistance.
Comparison with other materials: - (A) Metal: Conductivity decreases with temperature due to increased electron scattering.
- (C) Superconductor: Shows zero resistance below a critical temperature but loses superconductivity if temperature rises above it.
- (D) Polymer: Most polymers are insulators or poor conductors unless specially modified (e.g., doped).
Therefore, if a material's conductivity increases with temperature, it most likely behaves like an
intrinsic semiconductor.