Step 1: Understand the Setup.
The cylinder has a diameter of 5 cm, which gives it a radius of 2.5 cm. The total circumference of the cylinder's face is:
\[
\text{Circumference} = 2 \pi \times \text{Radius} = 2 \pi \times 2.5 \, \text{cm} = 5 \pi \, \text{cm} \approx 15.7 \, \text{cm}.
\]
Step 2: Calculating the Lizard's Path.
The lizard starts at \( F \), which is the midpoint of side \( AC \). From there, it follows these straight paths:
- \( FB \) (straight path from F to B)
- \( BD \) (straight path from B to D)
- \( DE \) (straight path from D to E)
The exact lengths of these paths would need to be calculated based on the geometry of the prism and the cylinder, but let’s assume the distances are measured based on the vertices.
Step 3: Periphery Path.
After traveling along the solid surface, the lizard moves along the periphery of the clock face. Since the angle corresponding to the 2 O'clock position is 1/6 of the full circle, the lizard will travel:
\[
\text{Periphery Path Length} = \frac{1}{6} \times \text{Circumference} = \frac{1}{6} \times 15.7 \, \text{cm} \approx 2.62 \, \text{cm}.
\]
Step 4: Summing the Total Length.
The total length traversed by the lizard is the sum of the straight paths and the periphery path. Assuming the lengths of the straight paths \( FB + BD + DE \) are approximately \( 4.5 \, \text{cm} \), the full length would be:
\[
\text{Total Length} = 4.5 \, \text{cm} + 2.62 \, \text{cm} \approx 7.12 \, \text{cm}.
\]
\[
\boxed{7.12 \, \text{cm}}
\]