Given below are two statements
Statement-I: When μ amount of an ideal gas undergoes adiabatic change from state (P1, V1, T1) to state (P2, V2, T2), then work done is
\(W = \frac{μR(T2 - T1)}{1 - γ}\)
,where
\(γ = \frac{Cp}{Cv} \)and R = universal gas constant.
Statement-II: In the above case, when work is done on the gas, the temperature of the gas would rise.
Choose the correct answer from the options given below.
The correct answer is (A) : Both statement-I and statement-II are true
\(W = \frac{μR(T2 - T1)}{1 - r}\)
for a polytropic process for adiabatic process r = γ
⇒ Statement I is true
In an adiabatic process
ΔU = –ΔW
⇒ If work is done on the gas
⇒ ΔW is negative
⇒ ΔU is positive or temperature increases
⇒ Statement II is true
The ratio of the fundamental vibrational frequencies \( \left( \nu_{^{13}C^{16}O} / \nu_{^{12}C^{16}O} \right) \) of two diatomic molecules \( ^{13}C^{16}O \) and \( ^{12}C^{16}O \), considering their force constants to be the same, is ___________ (rounded off to two decimal places).}
A heat pump, operating in reversed Carnot cycle, maintains a steady air temperature of 300 K inside an auditorium. The heat pump receives heat from the ambient air. The ambient air temperature is 280 K. Heat loss from the auditorium is 15 kW. The power consumption of the heat pump is _________ kW (rounded off to 2 decimal places).
0.5 g of an organic compound on combustion gave 1.46 g of $ CO_2 $ and 0.9 g of $ H_2O $. The percentage of carbon in the compound is ______ (Nearest integer) $\text{(Given : Molar mass (in g mol}^{-1}\text{ C : 12, H : 1, O : 16})$
Given: $ \Delta H_f^0 [C(graphite)] = 710 $ kJ mol⁻¹ $ \Delta_c H^0 = 414 $ kJ mol⁻¹ $ \Delta_{H-H}^0 = 436 $ kJ mol⁻¹ $ \Delta_{C-H}^0 = 611 $ kJ mol⁻¹
The \(\Delta H_{C=C}^0 \text{ for }CH_2=CH_2 \text{ is }\) _____\(\text{ kJ mol}^{-1} \text{ (nearest integer value)}\)
Consider the following reactions $ A + HCl + H_2SO_4 \rightarrow CrO_2Cl_2$ + Side Products Little amount $ CrO_2Cl_2(vapour) + NaOH \rightarrow B + NaCl + H_2O $ $ B + H^+ \rightarrow C + H_2O $ The number of terminal 'O' present in the compound 'C' is ______
Thermodynamics in physics is a branch that deals with heat, work and temperature, and their relation to energy, radiation and physical properties of matter.
A thermodynamic system is a specific portion of matter with a definite boundary on which our attention is focused. The system boundary may be real or imaginary, fixed or deformable.
There are three types of systems:
A system undergoes a thermodynamic process when there is some energetic change within the system that is associated with changes in pressure, volume and internal energy.
There are four types of thermodynamic process that have their unique properties, and they are:
The Zeroth law of thermodynamics states that if two bodies are individually in equilibrium with a separate third body, then the first two bodies are also in thermal equilibrium with each other.
The First law of thermodynamics is a version of the law of conservation of energy, adapted for thermodynamic processes, distinguishing three kinds of transfer of energy, as heat, as thermodynamic work, and as energy associated with matter transfer, and relating them to a function of a body's state, called internal energy.
The Second law of thermodynamics is a physical law of thermodynamics about heat and loss in its conversion.
Third law of thermodynamics states, regarding the properties of closed systems in thermodynamic equilibrium: The entropy of a system approaches a constant value when its temperature approaches absolute zero.