Question:

Given below are two statements:
Statement I: On heating with KHSO4, glycerol is dehydrated and acrolein is formed.
Statement II: Acrolein has fruity odour and can be used to test glycerol’s presence.
Choose the correct option

Updated On: Jan 4, 2025
  • Both Statement I and Statement II are correct.
  • Both Statement I and Statement II are incorrect.
  • Statement I is correct but Statement II is incorrect.
  • Statement I is incorrect but Statement II is correct.
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The Correct Option is C

Solution and Explanation

Glycerol, on heating with KHSO4, undergoes dehydration to give unsaturated aldehyde called acrolein. So, statement I is correct.Acrolein has piercing unpleasant smell. 
undergoes dehydration to give unsaturated aldehyde
So, statement II is incorrect.

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Concepts Used:

Alcohols, Phenols, and Ethers

Alcohol is formed when a saturated carbon atom bonds to a hydroxyl (-OH) group. It is an organic compound that contains a hydroxyl functional group attached to a carbon atom.

Phenol is formed when the -OH group replaces the hydrogen atom in benzene. It is an organic compound in which a hydroxyl group directly attaches to an aromatic hydrocarbon.

Ether is formed when oxygen atom bonds to two alkyl or aryl groups. It is an organic compound that has an oxygen atom that is connected to two aryl and alkyl groups.

Read More: Alcohol, Phenol, and Ethers