Question:

Given below are two statements, one is labelled as Assertion A and the other is labelled as Reason R
Assertion: \((CH_3)_2NH\) is less basic than \((CH_3)_3N\) in aqueous solution. 

Reason : Hyperconjugation in \((CH_3)_2NH\) is more than that in \((CH_3)_3N\).

In the light of the above statements, choose the correct answer from the options given below

Updated On: Apr 3, 2023
  • If both assertion and reason are true and reason is the correct explanation of assertion
  • If both assertion and reason are true but reason is not the correct explanation of assertion
  • If assertion is true but reason is false
  • If both assertion and reason are false
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The Correct Option is D

Solution and Explanation

Answer (d) If both assertion and reason are false

Assertion: \((CH_3)_2NH\) is less basic than \((CH_3)_3N\) in aqueous solution. (Not correct)

Reason : Hyperconjugation in \((CH_3)_2NH\) is more than that in \((CH_3)_3N\). (Not True and also not the correct reason)

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Concepts Used:

Amines

Amine is a type of compound which is derived from ammonia (NH3). According to Organic chemistry, they are basically classified as the functional groups of the organic nitrogen compounds that contain nitrogen atoms with a lone pair.

Amine - Types

Primary Amines:

It is formed when one hydrogen atom in ammonia is substituted by an alkyl or aromatic group. Amino acids and methyl amine are the best examples that why aromatic amines include aniline.

Secondary Amines:

Amines that have two organic substitutes either alkyl or aryl ones or both and are bound to the nitrogen together with one hydrogen are termed as secondary amines. For Example, Dimethylamine.

Tertiary Amines:

Tertiary Amines are the amines where the nitrogen consists of three organic substitutes. For example, Trimethylamine and EDTA.